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Phosphopantetheinyl fragment ions observed on the ACP2 of MycA upon incubation of acetoacetyl-S-MycA-ACP2 with Gln. A and C) the two phosphopantetheinyl elimination reactions of acetoacetyl-S-MycA-ACP2, B and D) the two phosphopantetheinyl elimination reactions of acetoacetyl-S-MycA-ACP2 treated with glutamine to form β-aminobutyryl-S-MycA-ACP2.
