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. Author manuscript; available in PMC: 2008 Aug 22.

Published in final edited form as: J Phys Chem B. 2007 Feb 27;111(11):2873–2885. doi: 10.1021/jp0663614

Table 4.

Comparison of empirical and experimental heats of vaporization and densities of neat benzene and toluene

		Drude		C22		Experimental data^a
	T(K)	V_m(Å³)	ΔH_vap	V_m(Å³)	ΔH_vap	V_m(Å³)	ΔH_vap
Benzene	298.2	147.46±0.71	8.01±0.03	151.97±0.72	7.53±0.03	148.00	8.08
Benzene	353.3	159.29±1.09	7.33±0.04	166.01±0.83	6.74±0.04	158.40^b	7.34^c
Toluene	298.2	175.64±0.38	9.12±0.04	180.43±0.19	8.47±0.05	176.51	9.08
Toluene	383.8	195.81±0.85	7.83±0.04	203.85±1.52	7.31±0.02	195.06^b	7.93^c

Experimental data from ref109.

From eqs 4–11.4a and 4–11.5 of ref124.

Experimental data from ref125.