Table 1.
Namea | L (nm)b | D (nm)c | Kd (sol; nM)d | Kd (cell; nM)e |
---|---|---|---|---|
Y16-DNP3 | 2.7 | 5.2 (±0.9) | 3.0 ± 1.0 | 1.5 ± 0.5 |
Y26-DNP3 | 4.4 | 6.9(±1.3) | 4.0 ± 1.0 | 1.2 ± 1.0 |
Y36-DNP3 | 6.1 | 10.4(±1.6) | 4.0 ± 1.0 | 1.5 ± 1.0 |
Y46-DNP3 | 7.8 | 13.1(±2.5) | 4.0 ± 1.0 | 1.6 ± 0.5 |
Y-shaped, trivalent (DNP3) ligand with n (= 16, 26, 36, or 46) bases in each of three single DNA strands that are annealed into the double stranded structure. Sequences of respective single strands are shown in Supplemental Table S1.
Estimated length (L) of each double-stranded arm of respective Yn-DNP3, based on length per base pair (0.34 nm).
Average rigid distances (D) between 5′ termini of Yn scaffolds for Yn-DNP3 ligands as determined by fluorescence resonance energy transfer measurements; numbers in parentheses indicate the range of distances between different termini due to some aplanarity and asymmetry in the rigid scaffolds (JB Lee, D Luo, in preparation).
Apparent dissociation constant for Yn-DNP3 ligands binding to IgE in solution, averaged from three experiments for each ligand (± standard deviation).
Apparent dissociation constant for Yn-DNP3 ligands binding to IgE-FcεRI on RBL cells, averaged from three experiments for each ligand (± standard deviation).