. Author manuscript; available in PMC: 2008 Aug 26.

Published in final edited form as: Chem Rev. 2007 May 27;107(6):2503–2545. doi: 10.1021/cr0509556

Table 24.

Desymmetrization of acylic amines using ARCM under solvent-free conditions with catalyst A (Figure 25).

entry	cat (mol%)	time (h)	yield (%)	ee (%)
1	2.5	0.2	76	>96
2	3.5	3.5	95	95
3	4	7	>98	97