. Author manuscript; available in PMC: 2008 Aug 26.

Published in final edited form as: Chem Rev. 2007 May 27;107(6):2503–2545. doi: 10.1021/cr0509556

Table 25.

Results of the highly concentrated carbonyl-ene reaction (Eq 10) with L14 and L15 from Figure 13.

entry	olefin	cat.	mol%	t (h)	yield (%)	ee (%)
1	A	(L14)₂Ti	0.1	48	98	98.2
2	A	(L14)(L15)Ti	0.1	48	85	97.6
3	A	(L14)₂Ti	0.01	72	76	97.2
4	A	(L14)(L15)Ti	0.01	72	49	97.9
5	B	(L14)₂Ti	0.1	48	89	99.4
6	B	(L14)(L15)Ti	0.1	36	96	98.2
7	C	(L14)₂Ti	0.1	48	83	98.4
8	C	(L14)(L15)Ti	0.1	48	96	98.4
9	D	(L14)₂Ti	0.1	36	92	97.1
10	D	(L14)(L15)Ti	0.1	36	>99	97.0