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. Author manuscript; available in PMC: 2008 Aug 26.
Published in final edited form as: Chem Rev. 2007 May 27;107(6):2503–2545. doi: 10.1021/cr0509556

Table 26.

Results of the highly concentrated carbonyl-ene reaction (Eq 10) with L14 and LI5 from Figure 13.

graphic file with name nihms-63649-t0078.jpg
entry olefin cat. mol% t (h) yield (%) ee (%)
1 E (L14)2Ti 0.1 24 >99 91.6
2 F (L14)(L15)Ti 0.01 42 42 91.8
3 G (L14)2Ti 0.1 48 97 92.2
4 G (L14)(L15)Ti 0.1 48 94 96.3