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. Author manuscript; available in PMC: 2008 Aug 26.
Published in final edited form as: Chem Rev. 2007 May 27;107(6):2503–2545. doi: 10.1021/cr0509556

Table 34.

One-pot asymmetric addition/diastereoselective epoxidation of cyclic enones with TBHP.

graphic file with name nihms-63649-t0103.jpg
entry substrates time (h)
products yield (%)
addition epoxidation
1 graphic file with name nihms-63649-t0104.jpg 45 4 graphic file with name nihms-63649-t0105.jpg 87
2 graphic file with name nihms-63649-t0106.jpg 44 4 graphic file with name nihms-63649-t0107.jpg 95
3 graphic file with name nihms-63649-t0108.jpg 44 4 graphic file with name nihms-63649-t0109.jpg 95