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Substrate scope in the asymmetric allylation of ketones with 1 : 2 Ti: BINOL ratio under highly concentrated conditions.
 | |||||
|---|---|---|---|---|---|
| entry | substrate | Ti:BINOL (mol %) |
IPA (equiv) |
ee (%) | yield (%) |
| 1 |  |
10 : 20 | 3 | 95 | 93 |
| 2 | 5 : 10 | 3 | 90 | 90 | |
| 3 |  |
10 : 20 | 3 | 89 | 87 |
| 4 | 5:10 | 3 | 79 | 85 | |
| 5 |  |
10 : 20 | 3 | 88 | 99 |
| 6 | 5 : 10 | 3 | 82 | 92 | |
| 7 |  |
10 : 20 | 3 | 91 | 96 |
| 8 | 5 : 10 | 3 | 85 | 99 | |
| 9 |  |
10 : 20 | 3 | 91 | 80 |
| 10 | 5 : 10 | 3 | 86 | 85 | |
| 11 |  |
10 : 20 | 3 | 87 | 99 |
| 12 | 5 : 10 | 3 | 79 | 99 | |
