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. Author manuscript; available in PMC: 2008 Aug 26.
Published in final edited form as: Chem Rev. 2007 May 27;107(6):2503–2545. doi: 10.1021/cr0509556

Table 45.

Continuous flow asymmetric hydroformylation of 3,3,3-trifluoropropene with the heterogeneous and homogeneous catalysts in Figure 42.

graphic file with name nihms-63649-t0137.jpg
entry total pressure
(atm)		 solvent time
(h)		 TON TOF
(h−1)		 iso/n ee (%)
(config.)
1 20 none 4 22 5.5 88/12 82 (S)
2 50 none 0.5 4.5 9 95/5 90 (S)
3 solution benzene 18 1152 64 95/5 93 (S)