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Enantioselective hydrosilylation of acetophenone with chelating chiral nitrogen-based ligands.
 | |||||
|---|---|---|---|---|---|
| entry | ligand | solvent | yield (%) | ee (%) | config. |
| 1 | A | none | 53 | 28 | S |
| 2 | A | toluene | 38 | 40 | S |
| 3 | B | none | 86 | 54 | S |
| 4 | B | toluene | 32 | 25 | S |
| 5 | C | none | 60 | 39 | S |
| 6 | C | toluene | 40 | 38 | S |
| 7 | D | none | 36 | 31 | S |
| 8 | D | toluene | 44 | 41 | S |
