Table 2.
Principle Bond Distances and Angles in [HIPTN3N]V(THF) and [HIPTN3N]V(NH3).
| [HIPTN3N]V(THF) | [HIPTN3N]V(NH3) | |
|---|---|---|
| V-N(1) | 1.9760(17) | 1.9555(8) |
| V-N(2) | 1.9675(18) | 1.9576(7) |
| V-N(3) | 1.9173(18) | 1.9520(8) |
| V-N(4) | 2.1627(18) | 2.1486(7) |
| V-Xaxial | 2.1399(15) | 2.1623(8) |
| N(1)-V-N(2) | 123.82(8) | 118.19(3) |
| N(1)-V-N(3) | 114.39(8) | 118.67(3) |
| N(2)-V-N(3) | 115.95(8) | 118.43(3) |
| N(1)-V-N(4) | 81.06(7) | 82.33(3) |
| N(1)-V-X | 94.94(7) | 97.57(3) |
| N(2)-V-N(4) | 82.72(7) | 82.90(3) |
| N(2)-V-X | 105.76(7) | 97.63(3) |
| N(3)-V-N(4) | 82.00(7) | 82.99(3) |
| N(3)-V-X | 92.87(7) | 96.57(3) |
| N(4)-V-X | 171.42(6) | 179.43(3) |
| X-V-N(1)-C | −20.4(2) | 1.45(8) |
| X-V-N(2)-C | −10.5(2) | 4.55(9) |
| X-V-N(3)-C | −15.3(2) | 0.17(8) |