Table 2.

Selected Mean Values or Ranges of Bond Distances (Å) and Angles (deg) of Cyanide-Ligated Clusters

[(Tp)VFe3S4(CN)3]2−a
V–N	2.188(4)	N–V–N	81.4(3)
V–S	2.34(1)	N–V–S	87.1(7)c
Fe–S4	2.27(3)	S–V–S	102.2(6)
Fe(n)–S(n)	2.26(1)e	V–S–Fe	73.2(4)c
Fe(n)–S(n′)	2.26(2)b	Fe–S4–Fe	70.55(5)–72.27(5)
V–Fe	2.74(1)	Fe–S–Fe	71.31(4)–72.73(4)
Fe–Fe	2.650(7)	S–Fe–S	103.5(1)–108.3(1)d
Fe–C	2.04(1)	C–Fe–S	103.1(1)–115.7(1)
[(Tp)2V2Fe6S8(CN)4]4−
core
V–N	2.192(4)	N–V–N	80.8(2)
V–S	2.35(2)	N–V–S	85.8(2)–88.7(2)
Fe(1,2)–S3	2.271(2)	S–V–S	101.0(1)–103.0(1)
Fe(n)–S(n)	2.252(4)f	V–S–Fe	72.13(8)–74.32(8)
Fe3–S(1,2)	2.252(1)	Fe–S–Fe	69.24(8)–73.82(8)
Fe(1,2)–S4	2.356(4)	S–Fe–S	104.2(1)–109.4(1)
V–Fe	2.74(4)	C–Fe–S	102.7(3)–121.7(3)
Fe1–Fe2	2.580(2)
Fe(1,2)–Fe3	2.701(1)
Fe–C	2.061(3)
bridge
Fe3–S4	2.352(2)	S4–Fe3–S4	111.17(8)
Fe3–S4	2.280(3)	Fe3–S4–Fe3′	68.83(8)
Fe3–Fe3	2.618(2)	S1/S2–Fe–S4′	114.8(1)/113.5(1)

^aAveraged under trigonal symmetry unless otherwise indicated.

^bn ≠ n′.

^cMean of six.

^dRange of nine.

^en = 1, 2, 3.

^fn = 1, 2.