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. Author manuscript; available in PMC: 2008 Sep 8.
Published in final edited form as: Inorg Chem. 2007 Feb 20;46(6):2286–2298. doi: 10.1021/ic061463u

Figure 5.

Figure 5

Formal diagrams of the porphyrin cores of [Fe(TPP)(CN)(1-MeIm)], [Fe(TPP)(CN)(Py)], [Fe(TMP)(CN)(1-MeIm)], and entity 1 of [K(18-C-6)][Fe(TMP)(CN)2]. The perpendicular displacements (in units of 0.01 Å) of the porphyrin core atoms from the 24-atom mean plane are displayed. In all diagrams, positive values of the displacement are towards the cyanide ligand. Also displayed on the formal diagrams are the averaged values of the chemically unique bond distances (in Å) and angles (in degrees). The numbers in parentheses are the esd’s calculated on the assumption that the averaged values were all drawn from the same population. The orientation of the imidazole or pyridine ligand is shown on these diagrams; the circle shows the position of the methyl group of the imidazole.