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. Author manuscript; available in PMC: 2008 Sep 9.
Published in final edited form as: J Am Chem Soc. 2005 Dec 14;127(49):17488–17493. doi: 10.1021/ja054935x

Table 4.

Influence of non-zero asymmetry parameters upon indole ring orientations and principal order parameters for tryptophans in gA channelsa.

Trp Δρ1 Δρ2 ΔSzz
9 −0.5° +5.0° +0.06
11 +1.0° +7.5° +0.06
13 −1.5° +8.5° +0.05
15 −1.0° +5.0° +0.05
a

The changes were determined by comparing the values of ρ1, ρ2 and Szz in Table 3, obtained using the calculated values of η (Table 1; above), with those previously obtained assuming η = zero (Table 4 of ref #1). The main insights from the nonzero η values are that the rings are somewhat more tilted in ρ2 than would otherwise be determined, and the rings exhibit even less 'wobble' motion with respect to the bilayer normal (higher Szz) than would be deduced if η were zero.