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. Author manuscript; available in PMC: 2008 Dec 10.

Published in final edited form as: Inorg Chem. 2007 Nov 15;46(25):10639–10646. doi: 10.1021/ic701338s

Table 2.

Ionization energies, band shapes, and He I and He II band areas for Cp₂V(S₂C₂H₂) and Cp₂V(bdt)

Cp₂V(S₂C₂H₂)
Band	I.E.^a (eV)	Band Width High (eV)	Band Width Low (eV)	Relative Area^b
				He I	He II
A	6.06	0.34	0.14	1	1
B	6.67	0.43	0.43	2.46	2.69
C	7.70	0.54	0.36	4.41	3.58

Cp₂V(bdt)
Band	I.E. (eV)	Band Width High (eV)	Band Width Low (eV)	Relative Area
				He I	He II
A	6.17	0.36	0.16	1	1
B	6.78	0.69	0.38	3.15	2.28
C	7.17	0.34	0.14	2.65	1.20

^a

Vertical ionization energy

^b

Areas are relative to Band A.