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. Author manuscript; available in PMC: 2008 Sep 14.

Published in final edited form as: J Am Chem Soc. 2006 Oct 18;128(41):13328–13329. doi: 10.1021/ja0640750

Table 2.

Initial Scope of Palladium-Catalyzed [3+2] TMM Cycloaddition Reactions.


Entry	Substrate	Product	T(°C)	Yield (%)^a	ee(%)
1			23 0	80 81	58 62
2			23 −25	76 63	72 82
3			23 −25	72 79	73 84
4			23 −25	84 72	73 83
5			−25	83	80
6	a: Ar = C₆H₄-4-OCH₃ b: Ar = C₆H₄-4-F		a: −25 b: −25	73 80	72 74
7			0	78	58

^a

Isolated yields