Table 3.
| ||||||
---|---|---|---|---|---|---|
entry | substrate 39 | cat. | time, min | product 40 | yield, %a | |
1 | b | AgBF4 | 2 | >99 | ||
2 | c | AgBF4 | 180 | 73b | ||
3 | TMSOTf | 600 | 70b | |||
4 | d | AgBF4 | 15 | 73 | ||
5 | e | AgBF4 | 15 | 84 | ||
6 | f | AgBF4 | 15 | 90 | ||
7 | g | AgBF4 | 10 | 86 | ||
8 | a | Cu(OTf)2 | 15 | 60c | ||
9 | h | Cu(OTf)2 | 180 | 81b | ||
10 | i | AuCl3 | 15 | 78b,c | ||
11 | j | Cu(OTf)2 | 15 | 91c |
Run on 1.0 mmol scale.
Run on 0.5 mmol scale.
Run in toluene.