Table 1.
Comparison of E. coli inactivation of several compounds in aqueous solution
| No. | Compound | Conditions c (concentration, contact time, aeration etc.) |
Log inactivation | Log inactivation
/ (mg/L·hr) |
|---|---|---|---|---|
| 1 | Iron(II,III) oxide nanoparticle a
Magnetite (Fe3O4), spherical < 50 nm, >60 m2/g |
9 mg/L, 1 hr, deaerated | < 0.1 | - |
| 2 | Oxidized nano-Fe0b | 9 mg/L, 1 hr, deaerated | ||
| 3 | 90 mg/L, 1 hr, air saturation | |||
| 4 | Iron (Fe0) powder a
< 10 μm, 0.26 m2/g |
1 g/L, 1 hr, deaerated | ||
| 5 | Fe(III) ion (FeCl3) | 1 mM, 1 hr, air saturation and deaerated | ||
| 6 | Fe(II) ion (FeSO4) | 0.1 mM, 1 hr, air saturation | ||
| 7 | 0.1 mM, 1 hr, deaerated | > 3 | - | |
| 8 | Nano-Fe0
< 100 nm, 31.5 m2/g |
9 mg/L, 10 min, deaerated | 3.4 d | 2.3 |
| 9 | 90 mg/L, 1 hr, air saturation | 2.6 d | 0.029 | |
| 10 | 90 mg/L, 1 hr, air saturation, 1 mM phosphate | 1.3 | 0.014 | |
| 11 | 45 mg/L, 1 hr, air saturation, 1 mM oxalate | 3.1 | 0.069 | |
| 12 | Nano-Ag0e
15 ∼ 20 nm |
10 mg/L, 1 hr, deaerated | 3.0 | 0.30 |
| 13 | 10 mg/L, 1 hr, air saturation | 4.1 | 0.41 |
Obtained from Sigma-Aldrich Co.
Oxidized for 2 hr under air saturation
Unless otherwise specified: pH = 8.0 (carbonate buffer), T = 21±0.5°C, air saturation indicates open system to atmosphere
From the data of Figure 2
Prepared by photoreduction of silver ion in aqueous solution containing poly(ethylene oxide)–poly(propylene oxide)–poly(ethylene oxide) block copolymers (Supporting Information, S3)