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. Author manuscript; available in PMC: 2008 Dec 26.
Published in final edited form as: J Am Chem Soc. 2007 Dec 5;129(51):15983–15996. doi: 10.1021/ja074900s

Figure 14.

Figure 14

Key molecular orbital at the transition state of an electrophilic reaction by FeIV=O species. (A) The anticancer drug bleomycin (BLM) (S=1, π-attack) from ref.80. The enzyme intermediates of (B) HmaS (S=2, π-attack) and (C) HPPD (S=2, σ-attack) from ref.81