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. Author manuscript; available in PMC: 2008 Oct 2.
Published in final edited form as: Org Lett. 2007 May 2;9(11):2051–2054. doi: 10.1021/ol062949h

Table 1.

Microwave assisted 1,3 dipolar cycloadditions of 10 and 12.a

graphic file with name nihms62339f6.jpg
dendrimer reactant product (R = ) 1H NMR (δ)b/yield
10 graphic file with name nihms62339t1.jpg
13a
graphic file with name nihms62339t2.jpg 7.62 ppm
98%
10 graphic file with name nihms62339t3.jpg
13b
graphic file with name nihms62339t4.jpg 8.07 ppm
95%
12 graphic file with name nihms62339t5.jpg
13c
graphic file with name nihms62339t6.jpg 7.93 ppm
98%
12 graphic file with name nihms62339t7.jpg
13d
graphic file with name nihms62339t8.jpg 7.87 ppm
97%
a

Reaction conditions: t-BuOH:H2O (1:1), 10 mol % Na ascorbate, 5 mol %CuSO4·5H2O. Microwave setting: Power-time control method, 100W, 10 min, Pmax= 65 psi, and Tmax= 100°C.

b

Chemical shift for the newly formed triazole protons.