Table 1.
Polymer | [M]o/[C] | Calcd./a | PSS/b | Rxn Temp (°C) | PDI | % Yieldc |
---|---|---|---|---|---|---|
7 | 10/1 | 1796 | 5170 | 24 | 1.18 | 57 |
8 | 18/1 | 3149 | 6532 | 24 | 1.30 | 59 |
9 | 35/1 | 6025 | 10445 | 24−40 | 1.52 | 59 |
10 | 50/1 | 8563 | 16966 | 24−40 | 1.56 | 64 |
Number average molecular weight by NMR.
Number average molecular weight by GPC using polystyrene standards.
Isolated yield after precipitation and silica column chromatography.