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IRMPD fragmentation of singly-iodinated myoglobin. Bottom: IRMPD FT-ICR mass spectrum of [M + 17H]17+ ions of singly-iodinated myoglobin. Top: b and y fragments observed. Fragments denoted with dashed line were observed without addition of iodine. Electrochemical iodination with pulsed cyclic potentials (2.5 s at 0.4 V vs SCE and 5 s at 0.0 V vs SCE, 240 cycles).
