TABLE 3.
1H and 13C chemical shifts for the B. cereus ATCC 10987 HF-PS
The values in parentheses are for the de-O-acetylated HF-PS.
| Residue | H1/C1 | H2/C2 | H3/C3 | H4/C4 | H5/C5 | H6a/C6 | H6b |
|---|---|---|---|---|---|---|---|
| α-d-GalNAc (A) | 5.23 | 4.32 | 4.23 | 4.23 | 3.93 | 4.06 | 3.78 |
| 97.6 | 48.2 | 68.7 | 68.7 | 70.0 | 69.5 | (3.78) | |
| (5.29) | (4.35) | (4.23) | (4.23) | (3.97) | (4.04) | ||
| (98.9) | (48.8) | (69.1) | 69.1 | (69.6) | (69.6) | ||
| β-d-ManNAc (B) | 5.04 | 4.66 | 5.15 | 3.94 | 3.65 | 3.92 | 3.83 |
| 98.6 | 50.8 | 75.8 | 75.5 | 75.6 | 61.4 | (3.83) | |
| (4.92) | (4.52) | (4.08) | (3.66) | (3.55) | (3.91) | ||
| (99.5) | (53.9) | (73.0) | (75.5) | (75.6) | (61.4) | ||
| β-d-GlcNAc (C) | 4.57 | 3.78 | 3.73 | 3.53 | 3.71 | 3.88 | 3.74 |
| 101.9 | 55.1 | 70.9 | 79.3 | 74.9 | 60.5 | (3.74) | |
| (4.57) | (3.77) | (3.72) | (3.51) | (3.70) | (3.88) | ||
| (101.6) | (55.4) | (70.9) | (79.3) | (74.9) | (60.5) | ||
| β-d-Gal (D) | 4.45 | 3.52 | 3.62 | 3.91 | 3.63 | 3.92 | 3.92 |
| 104.8 | 71.0 | 72.8 | 69.0 | 72.8 | 61.3 | (3.92) | |
| (4.46) | (3.52) | (3.62) | (3.91) | (3.60) | (3.92) | ||
| (105.0) | (71.0) | (72.8) | (69.0) | (72.8) | (61.3) |