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. 2008 Aug 18;105(33):11623–11627. doi: 10.1073/pnas.0804900105

Table 2.

Dynamic adsorption capacities of the benchmark MOFs for gaseous contaminants measured in grams of gas per gram of adsorbent

Gas MOF-5 IRMOF-3 MOF-74 MOF-177 MOF-199 IRMOF-62 BPL carbon Improvement factor*
Sulfur dioxide 0.001 0.006 0.194† <0.001 0.032 <0.001 0.033 5.88
Ammonia 0.006 0.105† 0.093 0.042 0.087 0.023 0.001 105
Chlorine ‡ 0.335† ‡ <0.001 0.036 0.092 0.190 1.76
Tetrahydrothiophene 0.001 0.007 0.090 <0.001 0.351† 0.084 0.123 2.85
Benzene 0.002 0.056 0.096 0.001 0.176† 0.109 0.155 1.14
Dichloromethane <0.001 0.001 0.032 <0.001 0.055† 0.019 0.053 1.04
Ethylene oxide 0.001 0.002 0.110 <0.001 0.095† 0.011 0.010 9.50

*Expresses the ratio of dynamic adsorption capacity of the best-performing MOF (†) to that of BPL carbon.

†Best-performing MOFs.

‡Experiments were not performed because of corrosion of the apparatus by chlorine.