TABLE 4.
Ion | λ0 | r (Å) | rs (Å) | r/rs = CF |
---|---|---|---|---|
44.9 | 3.47 | 2.05 | 1.69 | |
32.6 | 4.00 | 2.82 | 1.42 | |
23.4 | 4.52 | 3.93 | 1.15 | |
19.4 | 4.94 | 4.75 | 1.04 | |
17.4 | 5.29 | 5.29 | 1.00 |
λ0 is in units of S.cm2.equiv.−1. The λ0 and r data are from Appendix 6.2 and Table 6.2, respectively, of Robinson and Stokes (22). However, rs and r/rs were calculated afresh, rs from rs = 0.820/(λ0 ηo), which, with ηo = 0.008903 poise for water at 25°C, gives rs = 92.1/λ0.