Table 2.
Reaction pairs and conditions | Moser-Dutton k/s−1 | Marcus k/s−1 |
---|---|---|
bL-bH 2-vinyl (assuming ΔG = −60 mV, λ = 0.75, R = 7.02 Å) | 8.97 × 108 | 1.73 × 108 |
bL-bH 2-vinyl (assuming ΔG = −130 mV, λ = 0.75, R = 7.02 Å) | 2.15 × 109 | 5.68 × 108 |
bL-bL 4-vinyl (assuming ΔG = −0 mV, λ = 0.75, R = 10.54 Å) | 2.86 × 106 | 4.08 × 105 |
bL-bL 4-vinyl (assuming ΔG = −60 mV, λ = 0.75, R = 10.54 Å) | 6.51 × 106 | 1.25 × 106 |