Table 3.
Compound | Purity (%)a | Purity (%)d | Compound | Purity (%)a | Purity (%)d |
---|---|---|---|---|---|
2 | 98.9 | 94.8 | 11 | 97.5b | 97.2 |
3 | 95.6 | 95.1 | 12 | 96.9 | 91.6 |
4 | 98.1 | 99.5 | 13 | 98.7c | 99.4 |
5 | 99.6 | 99.6 | 14 | 96.4 | 97.8 |
6 | 95.4 | 98.3 | 15 | 98.4 | 98.4 |
7 | 98.0 | 100 | 16 | 97.1 | 96.6 |
8 | 91.8 | 91.2 | 17 | 96.4 | 99.5 |
10 | 100 | 98.4 | 18 | 99.1 | 100 |
Gradient of 88–95% of B in 22 min. Solvent A: 95% of acetonitrile/H2O and 0.045% of trifluoroacetic acid; Solvent B: acetonitrile/methanol/H2O = 85:10:5 and 0.045% of trifluoroacetic acid.
Gradient of 100% B in 30 min with same solvent system as described above.
Gradient of 90–100% B in 30 min with same solvent system as described above.
95% of acetonitrile/H2O in 30 min.