Table 1.

¹³C NMR and ¹H NMR Data of Zorbamycin (1) [D₂O, TSP, δ (ppm) (J = Hz)]^a

positionb	δC	δH
1	173.8
2	55.2	4.07 mc
3	49.8	2.88–3.06 m
4	179.0
5	43.1	2.78 mc, 2.69 dd (15.0, 9.0)
6	62.5	4.05 mc
7	168.2
8	167.6
9	115.5
10	154.8
11	13.8	2.16 s
12	170.8
13	60.4	5.09 d (8.0)
14	75.6	5.28 d (8.0)
15	100.8	5.25 d (3.5)
16	66.0	4.20 mc
17	74.4	3.64 mc
18	70.9	4.12 mc
19	73.4	3.99 mc
20	101.3	5.02 brs
21	71.2	4.06 mc
22	77.1	4.65 mc
23	67.4	3.82 mc
24	76.5c	3.84 mc
25	63.8	3.80 mc, 3.94 mc
26	160.8
27	137.6
28	120.0	7.30 s
29	139.6	7.91 s
30	172.2
31	51.8	3.82 mc
32	34.5	1.70 m
33	76.5c	3.74 mc
34	45.2	2.36 m
35	14.3	1.07 d (7.0)
36	179.6
37	63.6	4.29 s
38	74.3
39	28.3d	1.19 s
40	174.2
41	40.1	3.58 mc
42	42.1	2.92 m
43	180.3
44	41.4	3.58 mc, 3.90 mc
45	78.4	5.89 dd (9.0, 7.0)
46	175.0
47	128.3	8.16 s
48	151.0
49	165.9
50	17.3	0.92 d (8.0)
51	61.4	3.50 mc
52	28.6d	1.22 s
53	39.4	3.81 mc
54	35.5	2.80 mc
55	171.8

^aAssignment confirmed by the combination of DEPT, ¹H-¹H COSY, TOCSY, HSQC, and HMBC, spectra obtained at 500 MHz for ¹H and 125 MHz for ¹³C, respectively.

^bSee Figure 2 for hydrogen and carbon numbering of ZBM.

^cOverlapped signals.

^dInterchangeable signals.