Table 3. Comparison of Isolated Yields Obtained Through Conventional or MW-Assisted Heating in Various Solvents [63].
DKP | Yield (%) Δa | Yield (%) MWb | ||||||
---|---|---|---|---|---|---|---|---|
H2O | Toluene/2-BuOH | Toluene | t-BuOH | H2O | Toluene/2-BuOH | Toluene | t-BuOH | |
a | 41 | 8 | 20 | 62 | 73 | 14 | 18 | 10 |
b | <5 | 9 | 5 | 41 | 81 | <5 | 10 | 4 |
c | 57 | 6 | 5 | 10 | 70 | 6 | <5 | 12 |
d | 5 | 5 | 10 | 10 | 97 | 12 | 12 | 15 |
e | 7 | 32 | 24 | 37 | 68 | 17 | 14 | 24 |
f | <5 | <5 | 7 | 10 | 71 | 21 | 7 | 6 |
g | 7 | 5 | <5 | 8 | 63 | 15 | 8 | 8 |
h | 35 | 7 | 22 | 41 | 84 | 12 | <5 | 6 |
i | 33 | 51 | 29 | 88 | 70 | 10 | 14 | 10 |
j | 28 | 23 | 12 | 37 | 83 | 5 | 12 | <5 |
k | 89 | 88 | 83 | 93 | 93 | 73 | 70 | 76 |
Reactions were heated to reflux for 12 h.
Reactions were heated to 40°C above solvent boiling point for 10 min.