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. Author manuscript; available in PMC: 2009 Jan 1.
Published in final edited form as: Angew Chem Int Ed Engl. 2008;47(32):6073–6076. doi: 10.1002/anie.200801463

Table 1.

Acidity of methyl amide complexes 2 be.[a]

graphic file with name nihms65284f7.jpg
Entry Complex Ligand Yield [%][b] Keq[c] (pKa)THF
1 2 b Cp*2 33 0.249 ± 0.007 29.8
2 2 c Cp*CpMe4 42 0.524 ± 0.010 30.1
3 2 d CpMe42 51 1.05± 0.03 30.4
4 2 e rac-(ebthi) 22 0.079 ± 0.005 29.3
[a]

Reactions were run with 0.3 equiv [12]crown-4.

[b]

Yield determined by NMR spectroscopy and calculated using 1,3-dimethoxy-5-methylbenzene as an external standard.

[c]

Values are reported as the average of three runs ± standard deviation.