. Author manuscript; available in PMC: 2008 Nov 25.

Published in final edited form as: Inorg Chem. 2006 Jul 10;45(14):5438–5446. doi: 10.1021/ic060307k

Table 2.

Yield and Product Distribution for Reactions of 2 – 6 with Dioxygen

Complex	4-R	σ_P^a	Y_H (%)^b PhCHO	Y_R (%)^b 4-R-PhCHO	Y_R/Y_H^c	Y_R/Y_H^d	log (Y_R/Y_H)
2	Cl	0.23	24(2)	31(4)	1.26 (7)		0.10 (3)
3	F	0.06	28(2)	32(1)	1.16 (8)	1.22	0.06 (3)
4	CH₃	-0.17	34(1)	29(2)	0.85 (6)		-0.07 (3)
5	t-Bu	-0.20	33(1)	24(3)	0.78 (5)	0.79	-0.11 (3)
6	OCH₃	-0.27	34(4)	25(2)	0.74 (10)		-0.13 (6)

Hansch, C.; Leo, A.; Taft, R. W. Chem. Rev. 1991, 91, 165-195.

Y_H and Y_R represent the product yields of PhCHO and 4-R-PhCHO, respectively.

Ratios were determined from GC analytical data.

Ratios were determined by using ¹H NMR spectroscopy.