TABLE 1.
Formation of Allyl Enol Carbonates from Various Substituted Allyl 1H-imidazole-1-carboxylates
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Entry | OR | Yield of 1a | Ketone | Product | Yield |
1 |
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1b
80% |
2 | 4b | 88% |
2 | 5 | 6b | 99% | ||
3 |
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1c
91% |
2 | 4c | 76% |
4 | 5 | 6c | 76% | ||
5 |
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1d
97% |
2 | 4d | 80% |
6 | 5 | 6d | 94% | ||
7 |
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1e
85% |
5 | 6e | 89% |
8 |
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1f
95% |
5 | 6f | 96% |
9 |
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1g
97% |
5 | 6g | 92% |
10 |
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1h
100% |
5 | 6h | 76% |
Isolated yields of 1 from the reaction of 1,1′-carbonyldiimidazole and the corresponding allyl alcohol.