Table 2.

Expanded Sulfonamide Substrate Scope^a

entry	substrate	product(s)b		temp; time	yield (%)c
1	8	9	10	120 °C; 24 h	49 exo (9) 46 endo (10)
2	11	12	13	160 °C; 72 h	23 CA (12)d
3				160 °C; 72 h	59 CA (12) + 21 HA (13)
4	14	15		160 °C; 72 h	87d
5	16	17	18	210 °C, 72 h	56 CA (17, trans : cis = 1 : 1), 16 HA (18, trans : cis = 1 : 1)
6				210 °C; μW, 3 h	52 CA (17, trans : cis = 1 : 1), 20 HA (18, trans : cis = 1 : 1)
7	19	20	21	180 °C, 72 h	65 CA (20, trans : cis = 3 : 1) 33 HA (21, trans : cis = 3 : 1)
8	22	23		200 °C; 72 h	48
9	24	25	26	200 °C; 72 h	53 CA (25 only)
10				210 °C, μW, 3 h	55 CA (25) + 14 HA (26)
11	27	28		200 °C; 72 h	43

^aReaction conditions: 3 equiv Cu(ND)₂, 1 equiv Cs₂CO₃, DMF (0.08–0.1 M), temp, time.

^bSelectivity determined by analysis of the crude ¹H NMR spectrum, and by amount of the isolated adducts.

^cYield refers to amount of product isolated by chromatography on silica gel.

^dReaction run with Cu(OAc)₂ instead of Cu(ND)₂. CA = carboamination product, HA = hydroamination product, ND = neodecanoate.