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. Author manuscript; available in PMC: 2008 Dec 3.

Published in final edited form as: Inorg Chem. 2005 Jul 11;44(14):4947–4960. doi: 10.1021/ic050371m

(A). The normalized S K-edge XAS spectra of [M-S(C₆F₅)] complexes (M = Mn(II) , Fe(II) , Co(II) , Ni(II) , Cu(II) , and Zn(II) ]. (B) The 2^nd derivative spectra showing the shift in the 1s→ ψ^* transition as well as the edge transition between 2471.5 and 2473.0 eV. The circles and solid rectangles are color coded to indicate the pre-edge peak maxima and the edge transition respectively.

Inline graphic — (A). The normalized S K-edge XAS spectra of [M-S(C₆F₅)] complexes (M = Mn(II) , Fe(II) , Co(II) , Ni(II) , Cu(II) , and Zn(II) ]. (B) The 2^nd derivative spectra showing the shift in the 1s→ ψ^* transition as well as the edge transition between 2471.5 and 2473.0 eV. The circles and solid rectangles are color coded to indicate the pre-edge peak maxima and the edge transition respectively.