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. Author manuscript; available in PMC: 2009 Jul 23.
Published in final edited form as: J Am Chem Soc. 2008 Jun 27;130(29):9257–9259. doi: 10.1021/ja8031423

Figure 1.

Figure 1

Relative reactivity and selectivity (i-Pi vs n-Pr) of various electrophiles using n-BuPAd2, t-Bu3P and t-Bu2PPh. All reactions used Cs2CO3 (3 equiv), 10:1 toluene/H2O, Pd(OAc)2 (2 mol %), ligand (3 mol %), i-PrBF3K (1.1 equiv), 18 h, 100 °C.