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. Author manuscript; available in PMC: 2008 Dec 8.
Published in final edited form as: Inorg Chem. 2006 Nov 13;45(23):9185–9196. doi: 10.1021/ic0613457

Table 2.

Selected Bond Lengths and Angles of 5d vs. [HIPTMoN2][MgBr(THF)3].17

Bond 5d [HIPTMoN2][MgBr(THF)3]
N5-N6 (Nitrogen) 1.171(6) A 1.15 A
Mo-N5 (Dinitrogen) 1.882(4) A 1.86 A
Mo-N4 (Amine) 2.209(4) A 2.24 A
Mo-N3 (Amide) 2.022(4) A 2.02 A
N4-Mo-N5 174.09(17)° 178°
N4-Mo-N1 81.25(16)° 80°
Mo-N5-N6 174.2(4)° 178°
N5-N6-Na 110.7(4)°