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Deduced structure of the 1:2 complex, Mn2+(CO32-)(HCO3-)(OH2)3, formed in solution at high bicarbonate concentrations (> 50 mM) at pH 8.3. The arrows (DZZ and AZZ) show orientations of the principal axes of ZFS and 13C hyperfine coupling tensors. Their relative angle 90° corresponds to angle β derived from 13C HYSCORE simulations.
