. Author manuscript; available in PMC: 2008 Dec 11.

Published in final edited form as: Organometallics. 2006 Mar 27;25(7):1664–1675. doi: 10.1021/om051070n

Table 1.

Equilibrium Constants^a for 12 + NH₂Ar ⇌ 13 + Benzene ⇌ 14 +Benzene at 25°C.

Aniline (11)	K₁	K₂	K₃ = (K₁K₂)
a	1130	_^b	_^b
b	456	0.04	18
c	188	0.1	19
d	55	1	55
e	_^c	_^c	260
f	_^c	_^c	2190
g	_^c	_^c	2770

Equilibrium values are based on an average of 2–3 runs.

Concentration of 14a too low to detect

Concentrations of 13e–g too low to detect