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. Author manuscript; available in PMC: 2008 Dec 15.
Published in final edited form as: J Am Chem Soc. 2006 Dec 20;128(50):16384–16393. doi: 10.1021/ja063710z

Table 6.

Cross-Coupling Reactions of tert-Butyl Acrylate with Various Alkenyl Boron Compounds under Base-Free Conditions

graphic file with name nihms-61669-t0030.jpg
entry boron compound product yield (%)a
1 graphic file with name nihms-61669-t0031.jpg 2 + 3 64, 35
2 graphic file with name nihms-61669-t0032.jpg graphic file with name nihms-61669-t0033.jpg 92
3b graphic file with name nihms-61669-t0034.jpg graphic file with name nihms-61669-t0035.jpg 81
4c graphic file with name nihms-61669-t0036.jpg graphic file with name nihms-61669-t0037.jpg 86
5 graphic file with name nihms-61669-t0038.jpg graphic file with name nihms-61669-t0039.jpg 81
6c graphic file with name nihms-61669-t0040.jpg graphic file with name nihms-61669-t0041.jpg 91
a

Isolated yields.

b

TMS group was deprotected during column chromatography

c

The reaction time is 8 hours.