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. Author manuscript; available in PMC: 2008 Dec 15.
Published in final edited form as: J Am Chem Soc. 2006 Dec 20;128(50):16384–16393. doi: 10.1021/ja063710z

Table 9.

Cross-Coupling Reactions of Hexenyl Boronic Ester with Various Alkenes in the Presence of Ligand

graphic file with name nihms-61669-t0054.jpg
entry olefin product yield (%)a
1 graphic file with name nihms-61669-t0055.jpg graphic file with name nihms-61669-t0056.jpg 92
2 graphic file with name nihms-61669-t0057.jpg graphic file with name nihms-61669-t0058.jpg 89
3 graphic file with name nihms-61669-t0059.jpg graphic file with name nihms-61669-t0060.jpg 88
4 graphic file with name nihms-61669-t0061.jpg graphic file with name nihms-61669-t0062.jpg 87b
5 graphic file with name nihms-61669-t0063.jpg graphic file with name nihms-61669-t0064.jpg 91c
a

Isolated yields.

b

The ratio of 1,4- and 1,3-diene was 6:1 by 1H-NMR analysis.

c

The .ratio of E to Z isomer was 9:1 by 1H-NMR analysis.