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Crystal structures of the monoanionic and neutral [Mo(mdt)3]z and [Mo(tbbdt)3]z complexes. Average values are reported.
| [Mo(mdt)3]1- | [Mo(mdt)3] | [Mo(tbbdt)3]1- | [Mo(tbbdt)3] | ||
|---|---|---|---|---|---|
| Mo-S (Å) | 2.37 | 2.37 | 2.38 | 2.36 | |
| S-Mo-S (°) | 80.5 | 81.3 | 81.3 | 81.5 | |
| Bailar Twist (°) | 1.6 | 2.4 | 31.7 | 1.9 | |
| Chelate Fold (°) | 4.0 | 15.8 | 10.9 | 23.8 | |
