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. Author manuscript; available in PMC: 2009 Jan 9.
Published in final edited form as: J Org Chem. 2006 Nov 24;71(24):9172–9177. doi: 10.1021/jo061439y

Table 2.

Reaction of carbenoids with S-allyl glutathione.

graphic file with name nihms61522f5.jpg
R Product (% Yield)
1 CO2Et 8 (45)
2 C6H5 9 (45)
3 CO(CH2)14Me 10 (38)
4 (CH2)9Mea 11 (35)
5 (CH2)2(CF2)5CF3a 12 (32)
a

Diazo precursors to 11 and 12 were prepared from the hydrazones with Pb(OAc)4 and were used immediately.