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. Author manuscript; available in PMC: 2009 Oct 15.
Published in final edited form as: J Am Chem Soc. 2008 Sep 18;130(41):13709–13717. doi: 10.1021/ja804087r

Figure 1.

Figure 1

Plot of kobsd versus [n-BuOMe] in pentane cosolvent for the rearrangement of 7d (0.004 M) by LDA (0.075 M) at 15 °C. The curve depicts an unweighted least-squares fit to kobsd = k[n-BuOMe]n + k’ (k = (3.0 ± 0.1) × 10-3, n = -1.10 ± 0.05, k’ = (4.1 ± 0.1) × 10-4).