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. Author manuscript; available in PMC: 2009 Oct 15.
Published in final edited form as: J Am Chem Soc. 2008 Sep 18;130(41):13709–13717. doi: 10.1021/ja804087r

Figure 2.

Figure 2

Plot of kobsd versus [LDA] in 1.3 M n-BuOMe/pentane for the rearrangement of 7d (0.004 M) at 15 °C. The curve depicts an unweighted least-squares fit to kobsd = k[LDA]n + k’ (k = (6.3 ± 0.2) × 10-3, n = 0.49 ± 0.09, k’ = (7.9 ± 0.2) × 10-4). k’ (see ·) was set to equal k’ in Figure 3.