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. Author manuscript; available in PMC: 2009 Oct 6.
Published in final edited form as: Inorg Chem. 2008 Sep 11;47(19):8884–8895. doi: 10.1021/ic8009496

Figure 6.

Figure 6

Formal diagrams of the porphyrinato cores of a) [Fe(TPP)(2-MeHIm)]·(l,10-phen) (A); b) [Fe(TPP)(2-MeHIm)]·(l,10-phen) (B, Molecule 1); c) [Fe(TPP)(2-MeHIm)]·(l,10-phen) (B, Molecule 2); d) [Fe(OEP)(2-MeHIm)]·(l,10-phen) Molecule 1; e) [Fe(OEP)(2-MeHIm)]·(l,10-phen) Molecule 2. Illustrated are the displacements of each atom from the mean plane of the four pyrrole nitrogen in units of 0.01 Å. Positive values of displacement are toward the imidazole ligand. The diagrams also show the orientation of the imidazole ligand with respect to the atoms of the porphyrin core. The location of the methyl group at the 2-carbon position is represented by the circle.