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. Author manuscript; available in PMC: 2009 Oct 6.
Published in final edited form as: Inorg Chem. 2008 Sep 11;47(19):8884–8895. doi: 10.1021/ic8009496

Table 2.

Variable-Temperature Mössbauer Parameters (mm/s) for [Fe(TPP)(2-MeHIm)]·(1,10-phen) and [Fe(OEP)(2-MeHIm)]·(1,10-phen)

[Fe(TPP)(2-MeHIm)]·(1,10-phen)
T (K) 298 200 100 20
ΔEQ 1.46 1.65 2.06 2.12
δFe 0.80 0.86 0.88 0.90
[Fe(OEP)(2-MeHIm)]·(1,10-phen)
T (K) 295 200 100 25 4.2
ΔEQ 1.73 1.80 1.92 2.01 1.96
δFe 0.82 0.89 0.89 0.90 0.94