[i] |
Concentration of species i (mol l−1) |
|
|
(i) |
Activity of i (mol l−1) |
|
|
ai |
Effective diameter of ion i
|
|
Ref. [33] |
A |
Parameter A for Debye-Hükel limiting law |
0.51144 |
|
B |
Parameter B for Debye-Hükel limiting law |
107.517
|
|
fi |
Activity coefficient for species i |
|
|
J |
P/(HPO42−) |
|
|
m |
Total ionic strength of the solution |
|
|
P |
Total phosphate concentration (mol l−1) |
|
|
S |
Concentration of ion pairs (H2PO4)22−
|
|
|
T |
Total concentration of ion pairs CaHPO4o and CaH2PO4+
|
|
|
U |
Total concentration of ionpairs MgHPO4o and MgH2PO4+
|
|
|
Zi |
Valence of ion I |
|
|
|
First dissociation constant of phosphoric acid |
10−2.127
|
Ref. [34] |
|
Second dissociation constant of phosphoric acid |
10−7.20
|
Ref. [35] |
|
Third dissociation constant of phosphoric acid |
10−12.325
|
Ref. [36] |
|
Ionic product for water |
10−13.99
|
Ref. [37] |
|
Dissociation constants of CaHPO40 ion-pair |
10−2.3874
|
Ref. [36] |
|
Dissociation constants of CaH2PO4+ ion-pair |
10−0.9138
|
Ref. [36] |
|
Dissociation constants of MgHPO40 ion-pair |
10−2.852
|
Ref. [38] |
|
Dissociation constants of MgH2PO4+ ion-pair |
10−1.276
|
Ref. [38] |