Table 1.
The β- and γ-shift values for selected 13C′ resonances in [L]SSI and [V]SSI.
| Residue | β-shift (Hz) | γ-shift (Hz) |
|---|---|---|
| Val13 | 6.1 | 2.5 |
| Val16 | 6.1 | 1.9 |
| Val31 | n.d. | 2.6 |
| Leu33 | n.d. | 3.2 |
| Leu53 | 7.0 | n.d. |
| Val78 | 6.6 | 1.9 |
| Leu80 | 6.5 | 1.6 |
| Val82 | 7.1 | 2.9 |
| Val85 | 6.1 | 2.3 |
| Val91 | n.d. | 2.2 |
| Val96 | 6.1 | n.d. |
All of the data were collected on a Varian XL-300 spectrometer (13C frequency of 75.4 MHz) under the conditions of pH* 7.3 at 50 °C. These isotope shifts were found to be independent of pH* in the range from 6 to 10. The notation “n.d.” indicates that the isotope shift was not detected.