Table 1. Overview of frequently used definitions of glycosidic torsion angles.
Angle | NMR style | C − 1 crystallographic style | C + 1 crystallographic style |
---|---|---|---|
ϕ | H1—C1—O—C′x | O5—C1—O—C′x | O5—C1—O—C′x |
ψ | C1—O—C′x—H′x | C1—O—C′x—C′x−1 | C1—O—C′x—C′x+1 |
ψ [(1–6)-linkage] | C1—O—C′6—C′5 | C1—O—C′6—C′5 | C1—O—C′6—C′5 |
ω | O—C′6—C′5—H′5 | O—C′6—C′5—C′4 | O—C′6—C′5—O′5 |