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. Author manuscript; available in PMC: 2009 Nov 5.
Published in final edited form as: J Am Chem Soc. 2008 Oct 9;130(44):14745–14754. doi: 10.1021/ja805067h

Figure 3.

Figure 3

(a) Pseudo first order plot of kobs vs. [TEMPO•] at 298 K and (b) Eyring plot for the reactions of RuIIimH(D) with TEMPO• in MeCN [k3H = ● (no CH3OH), ▲ (25 mM CH3OH); k3D = ■ (25 mM CD3OD)]. The Eyring plot also shows the calculated k3H,calc and k3D,calc values in dashed lines (---) using the Marcus cross relation (see below).